Turning CO2 Into Building Materials: Mineral Carbonation International Tour

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Welcome to Engineering with Rosie. I am here today on the campus of the University of Newcastle where Mineral Carbonation International have their pilot plant facility. Mineral Carbonation International are a company that's doing carbon capture and utilization and I recently made a video on a broad range of technologies that you can use to take CO2 that has been captured from the atmosphere or from like flue gases and turn it into a useful product. In that video, I talked about how I thought that to assess the viability of a CCU technology, it needed to be three things. It needed to be economic, it needed to be durable, and it needs to be scalable. And in that video I went through a lot of like really trendy CCU things like making diamonds or alcohol. But none of those really ticked all the boxes, especially the scalability one but mineral carbonation was one of a couple of processes where I really did see the potential for a large scale, a large amount of tonnes of CO2 that could be taken permanently out of the atmosphere. So I'm really excited to be here at MCi, I'm gonna take a look at their pilot plant, get explanations of how their product work and have a look at some of their pilot manufacturing facilities and hear about their plans for scale up into the future. Mineral carbonation involves reacting carbon dioxide as a gas with minerals that contain calcium or magnesium to permanently convert the CO2 into a solid calcium or magnesium carbonate products. There's a range of minerals that are suitable for the process including naturally occurring magnesium silicates and industrial byproducts such as steelmaking slags. The steelmaking slags are attractive because they present in a location that is also a source of CO2, and there's a ready access to product markets. What's really exciting about the natural minerals is that they're available in massive quantities, there's actually more of these minerals available than there is CO2. So in terms of the quantities of materials available, there is a massive potential for CO2 abatement with mineral carbonation. It's the acceleration of a natural process, so these minerals react naturally with CO2. In the environment, this takes millions of years and we've developed a technology that scales that up to happen in minutes. And so it's useful as an industrial process. Process starts with the feedstock for material. So as I mentioned, it's a source of calcium or magnesium. So that could be natural minerals like this rock, which is called serpentinite, it's a magnesium silicate rock. It can also the industrial byproducts, such as steelmaking slag, that contain calcium. Our process takes those feedstocks and then puts it through a pre-processing step that enhances their reactivity with CO2. So that includes grinding the mineral into a powder, in some cases involves thermal treatment and that improves the reactivity of the mineral. That technology can use either concentrated CO2 or it can also use industrial flue gas direct from an industrial process without prior concentration. So that's one of the big advantages of MCi's technology. What we've studied is the economics of the process at different CO2 concentrations. And what we find that if the CO2 concentration is above 15%, then it's more economical to directly capture the flue gas with MCi's technology. If it's more dilute, then there's obviously a lot of other technologies that are available that can pre concentrate the CO2. So it's technically possible to capture it down to about 5% CO2 but economically about 15% is the cutover point and MCi has developed a proprietary process where this carbonation reaction happens at low pressure using the flue gas and also at low temperature which is really important for minimizing the capital cost of the equipment and the energy consumption of the process. This is serpentinite? to extract another mineral. We then grind those materials into a powder and then combine that powder with water to make a slurry. And then that slurry is contacted with CO2 in MCi's process and we produce a high purity calcium or magnesium carbonate product powder and amorphous silica output material. And then these outputs can be used in a range of end products including concrete so the silica can be used in concrete to reduce its emissions intensity. And the magnesium carbonate can be used in plasterboards to make a low emissions plasterboard containing up to 50% CO2 by mass. So it's actually a carbon negative construction we can displace between 20 and 30% of the cement content in the concrete is similar to conventional SCM such as fly ash. That's obviously really exciting because we're abating CO2 to produce that material and then that material is reducing the emissions footprint further in its application. The way that we envisage our business model working is that as we scale up through the intermediate stages, we'll be able to sell the products to make profit in useful materials. As we scale up to really large scales, we think that it could be profitable just that we can reduce the costs efficiently, that it would be viable just based on CO2 pricing alone. So with enough economies of scale, we think we can get the unit cost low enough. And as we talked to, we're working with a range of potential customers of our products as we talk to them were continuously uncovering new applications for the materials, some of the applications are things that we never envisaged, for example, you know, as a filler in carpet backing. You might not know that the carpets that are used in office buildings contain a lot of calcium carbonate as part of the as a filler. And that's a natural use for our material where we could be replacing mined calcium carbonate with something that's actually locking away CO2. What are some of the other applications that people are talking to you about? So some of the other applications include refractories, materials that are used in high temperature processes, glassmaking, other additives at different stages of the cement manufacturing process, fire retardant materials for firefighting or adding into construction products to improve their fire performance, so there's a wide range of different applications. Today, we're at our pilot plant facility at the Newcastle Institute for Energy and Resources. What we have here is a combination of small scale lab equipment, and also a small continuous pilot plant, which is like a mini industrial facility for demonstrating the technology. In front of us is a series of small scale reactors that we use for characterizing different potential feedstock materials. So we'll be conducting your reaction under different process conditions to find the optimum conditions for treating a particular sample. So in this step, we have a slurry of the mineral powder, we're injecting CO2 into the reactors and monitoring the CO2 uptake over time. So inside the reactor, it's a stirred vessel with an impeller which is agitating the slurry just in here, the associated equipment is supplying a controlled flow rate and composition of simulated flue gas into the vessel. We also have control of pressure and temperature so tightly controlling the reaction conditions and then we're taking samples of the slurry which is inside the reactor and analyzing that to track the reaction progress. So, you take the slurry, you stir it, you- -inject the CO2. CO2 is absorbed into the liquid and reacts with the mineral, comes out as a slurry and then we filter, filter that and and dry the end product. So how much energy does it use? Carbonation is a thermodynamically favored process. That means that the overall process actually releases energy in the form of heat. But we do need to put energy in order to speed up the process to be industrially useful. So the main energy consuming steps are for grinding the rock and any handling of the gas that are compressing or blowing the CO2 through the system. Typically, even if we were using fossil fuel derived energy for powering our process, we'd be around 80 to 90% efficient in terms of the overall CO2 removal. Obviously, it's improved further if you're using a low emissions, energy source These equipments are obviously really small scale, and we're using that for characterizing the reactivity of the materials. What we have at the back of the building is a small scale, continuous process. So it's like a mini industrial process where we're putting through up to about 100 kilograms per day of mineral in a continuous reactor. So we're continuously pumping the slurry and reacting the CO2 and producing the different output materials. And we're using this to characterize basically the engineering performance of the process and gathering the information that we need to further scale up the technology. Our process uses standard equipment, agitated tanks, pumps and reactors, there's no new novel devices that are needed to make our process work. It's more about engineering the equipment in a way that's best suited for our process. All standard technologies that are used in mining or mineral extraction or chemical process. So this process is putting through about 100 kilograms of mineral per eight hour shift between 20 to 30 kilograms of CO2 abatement. The moment we're designing an industrial scale demonstration facility that will be taking CO2 from an actual industrial process at about 1000 to 3000 tonnes per year. And we are aiming to commission that plant around the middle of next year. We're aiming to be rolling out our first commercial plants within around five years time that will be at the scale of around 100,000 tonnes of CO2 per year. And then scaling up to the million tonnes scale over the next 10 to 15 years. We're seeing a huge interest in the technology, both from CO2 emitters that are looking for a solution for their CO2, and also companies that are interested in using our output materials as low carbon embodied inputs to their manufacturing processes. And our team is expanding rapidly in order to meet that growth in demand. So we're always on the lookout for bright engineers and scientists to come and join our team at MCi. We're really fortunate in the Newcastle region that there's so many young, bright engineers and a lot of experience from the existing industries that we've got here that we can leverage to help make this a reality for a lot of the technologies that we're using have a lot in common with existing technologies that are used in in mining or mineral processing or chemical manufacture. So there's a lot of skills that we can use in the new low carbon economy. Thanks so much to Mineral Carbonation International for letting me inside their facility and letting me film in there. It's not always easy to get these cool cutting edge technology companies to let us actually physically see what you're doing. So I really appreciate the access and answering all my questions. I think that the most important thing to know is the scale of time that they have been working on this technology you might have seen recently I did a video on Boston Metal where I went through their technology development process, it's going to take about 20 years from that first scientific discovery through to an actual meaningful volume of their product being sold and you know, displacing "dirty" steel in the market. And Mineral Carbonation International, it's a really similar timeframe, it's been about 10 years since they have been funded, will be about another 10 years until we're seeing hundreds of thousands or millions of tonnes of their product. And that's the scale that we need to make a meaningful difference to the amount of CO2 in the atmosphere. One of the other thing I really like about this company and one of the reasons why I came up here to Newcastle region was that it's a big coal mining region, a big coal export port, and actually the facility next door is working on some research related to coking coal. I think it's really interesting that you don't hear a lot of talk in the energy transition about jobs. In Australia, at least, the debate about phasing out coal is very much tied to jobs in the coal industry. But MCi are scaling up and they're looking for engineers and scientists and the type of people that they need, the experience that they need comes straight out of the mining industry. Their processes or their equipment, it's really similar stuff from mining and processing of minerals. So I think that that's really interesting that the energy transition and solutions to climate change. It doesn't need to be a trade off money and jobs and sacrificing these old industries. There are plenty of companies like this that are really keen to get those skills that people have developed in the mining industry and then apply them to these new technologies. So to me that's really, really exciting. And you say heaps or it over this region. Thanks to Mineral Carbonation International for giving me this great tour and interview. As always, thank you to my Patreon team who support the channel. If you'd like to join us, I'll put a link in the description and thanks to you all for watching. I'll see you in the next video!
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Channel: Engineering with Rosie
Views: 19,284
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Keywords: renewable energy, mechanical engineering, circular economy, clean energy transition, climate change, green economy, stem, women in stem, stem education, Rosemary Barnes, Engineering with Rosie, women in engineering, technology, environmental science, environmental engineering, engineering tutorials, sustainability, science news, engineering news, explainer video, engineering explained, new energy, CCU, CCUS, mineral carbonation, carbon capture, sequestration
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Length: 13min 20sec (800 seconds)
Published: Thu Sep 22 2022
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